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Local Enrichment of Active Element Y in Y-modified PVD Films on Mild Steel Substrate

LIU Changqing WU Weitao JIN Zhujing DAI Shaoxia WANG Wenhao Corrosion Science Laboratory , Institute of Corrosion and Protection of Metals , Academia Sinica , Shenyang , 110015 , ChinaInstitute of Metal Research , Academia Sinica , Shenyang , 110015 , ChinaTo whom correspo

材料科学技术(英)

By means of EPMA,SIMS and XTEM tech- niques,the element distribution at the transition zone of Y-modified ion plated titanium and titanium nitride film on A3 steel substrate and the variation of the element content on the surface of the evaporation source before and after service were studied in detail.A mode was proposed in terms of preferential evaporation and micro-tunnel trans- portation of Y at the interface of film/substrate.

关键词: Y-enrichment , null , null , null

Laser Surface Modification of Ti-6Al-4V with Addition of Pr

CHE Chengwei ZHANG Zhiming DONG Xianglin LIU Chengliang Harbin Institute of Technology , Harbin , 150006 , ChinaInstitute of Metal Research , Academia Sinica Shenyang , 110015 , China

材料科学技术(英)

The behaviour of oxidation at elevated tem- peratures and fretting in the laser-alloyed layer of Ti-6Al-4V with the addition of Pr was studied. The results show that the addition of Pr changes the structure of oxide scale of Ti-6Al-4V,controls the short-range diffusion of oxygen to the scale/substrate interface and increases the adhe- sion and ductility of the scale,thus changing the oxidation kinetics and considerably reducing oxidation rate.The analysis of fretting test shows that the existence of high hardness layer in the al- loyed zone,fine dendrites perpendicular to the sur- face of the high hardness layer and the oxide scale produced during fretting at elevated temperatures are all beneficial to the improvement of wear resist- ance.

关键词: laser modification , null , null , null

Microstructure and Properties of Laser Surface Alloying 304 Stainless Steel with Si

LI Ruiguo FENG Jun FENG Zhongchao Corrosion Science Laboratory.Institute of Corrosion and Protection of Metals. Academia Sinica , Shenyang , 110015 , ChinaInstitute of Metal Research , Academia Sinica.Shenyang 110015 , China

材料科学技术(英)

Silicon was added to the surface of 304 stain- less steel by laser melting the sprayed preplaced Si powders.The optical microscopy,X-ray diffraction and EPMA were employed to investigate the microstructure and chemical composition of the laser surface alloyed layer.The hardness of the al- loyed layer was measured by microhardness test and wear resistance was evaluated by scratch test. Corrosion resistance of laser alloyed sample was studied in 1N H_2SO_4+0.1N NaCl and 0.5N HCl+0.5N NaCl aqueous solutions.A microcrystalline intermetallic compound coating with smooth surface and good chemical homogeneity without porosity and crack is ob- tained.The hardness is about 720 HV.The wear re- sistance is 2 times better than that of the substrate. The corrosion resistance of the laser alloyed sample is much better than that of 304 stainless steel sample.

关键词: laser , null , null , null , null

Technical note: Research and development of localized corrosion rate monitoring instrument for nonpassivable metal in corrosive media

Corrosion

This paper introduces the design of a localized corrosion rate monitoring instrument that can monitor and evaluate the maximum and stable localized corrosion rate of a nonpassivable metal in a corrosive environment by measuring the current density in a corrosion sensor with an occluded anode.

关键词: instrument;localized corrosion rate;monitor

Study on Process Parameters Optimization of Sheet Metal Forming Based on PFEA/ANN/GA

Juhua HUANG , Jinjun RAO , Xuefeng LI

材料科学技术(英)

Sheet metal forming is widely applied to automobile, aviation, space flight, ship, instrument, and appliance industries. In this paper, based on analyzing the shortcoming of general finite element analysis (FEA), the conception of parametric finite element analysis (PFEA) is presented. The parametric finite element analysis, artificial neural networks (ANN) and genetic algorithm (GA) are combined to research thoroughly on the problems of process parameters optimization of sheet metal forming. The author programs the optimization scheme and applies it in a research of optimization problem of inside square hole flanging technological parameters. The optimization result coincides well with the result of experiment. The research shows that the optimization scheme offers a good new way in die design and sheet metal forming field.

关键词: Sheet metal forming , null , null , null

Metal Dusting-Mechanisms and Preventions

J.Q.ZHANGD.J.YOUNG

中国腐蚀与防护学报

Metaldusting attacks iron, low and high alloy steels and nickel-or cobalt-base alloys by disintegrating bulk metals and alloys into metal particles in a coke deposit. It occurs in strongly carburising gas atmospheres (carbon activity aC>1) at elevated temperatures (400 ℃~1000 ℃). This phenomenon has been studied for decades, but the detailed mechanism is still not well understood. Current methods of protection against metal dusting are either directed to the process conditions-temperature and gas composition-or to the development of a dense adherent oxide layer on the surface of the alloy by selective oxidation. However, metal dusting still occurs by carbon dissolving in the base metal via defects in the oxide scale. The research work at UNSW is aimed at determining the detailed mechanism of metal dusting of both ferritic and austenitic alloys, in particular the microprocesses of graphite deposition, nanoparticle formation and underlying metal destruction. This work was carried out using surface observation, cross-section analysis by focused ion beam and electron microscopic examination of coke deposits at different stages of the reaction. It was found that surface orientation affected carbon deposition and metal dusting at the initial stage of the reaction. Metal dusting occurred only when graphite grew into the metal interior where the volume expansion is responsible for metal disintegration and dusting. It was also found that the metal dusting process could be significantly changed by alterations in alloy chemistry. Germanium was found to affect the iron dusting process by destabilising Fe3C but increasing the rate of carbon deposition and dusting, which questions the role of cementite in ferritic alloy dusting. Whilst adding copper to iron did not change the carburisation kinetics, cementite formation and coke morphology, copper alloying reduced nickel and nickel-base alloy dusting rates significantly. Application of these fundamental results to the dusting behaviour of engineering alloys is discussed.

关键词: metal dusting , null , null , null , null , null

Review On Research And Development Of Magnesium Alloys

Z. Yang , J.P. Li , J.X. Zhang , G.W.Lorimer , J. Robson , null , null , null , null

金属学报(英文版)

The current research and development of magnesium alloys is summarized. Several aspects of magnesium alloys are described: cast Mg alloy, wrought Mg alloy, and novel processing. The subjects are discussed individually and recommendations for further study are listed in the final section.

关键词: Magnesium alloys , null , null

Introduction to atmospheric corrosion research in China

Science and Technology of Advanced Materials

In this paper, we introduce the research on atmospheric corrosion in China. We describe the climate characteristics and the classification of atmospheric corrosivity across the whole country. We also describe the rusting evolution under simulated wet/dry cyclic conditions. (C) 2007 NIMS and Elsevier Ltd. All rights reserved.

关键词: atmospheric corrosion;corrosivity;rusting evolution;weathering steels;rust;mechanism;so2;o-3;no2

THE CHANGING ROLE OF THE NATIONAL LABORATORIES IN MATERIALS RESEARCH

WADSWORTH Jeffrey and FLUSS Michael(Chemistry and Materials Science Directorate , Lawrence Livermore National Laboratory , Livermore , CA 94551)

金属学报(英文版)

The role of the National Laboratories is summarized from the era of post World War II to the present time. The U.S. federal government policy for the National Laboratories and its influence on their materials science infrastructure is reviewed with respect to .determining overall research strategies, various initiatives to interact with industry (especially in recent years),building facilities that serve the nation, and developing leading edge research in the materials sciences. Despite reductions in support for research in the U.S. in recent years, and uncertainties regarding the specific policies for Research &Development (R&D) in the U.S., there are strong roles for materials research at the National Laboratories. These roles will be centered on the abilities of the National Laboratories to field multidisciplinary teams, the use of unique cutting edge facilities, a focus on areas of strength within each of the labs,increased teaming and partnerships, and the selection of motivated research areas. It is hoped that such teaming opportunities will include new alliances with China, in a manner similar, perhaps, to those recently achieved between the U.S. and other countries.

关键词: : U.S. Materials Science. U.S. National Laboratories and Facilities , null

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